#4 12/126 against Zimbabwe at Harare (2005)
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Irfan Pathan was in sublime form when India toured Zimbabwe in 2005. It was only his second tour outside the subcontinent and Pathan wreaked havoc in Zimbabwe.
Having already sounded a warning in the first Test, taking 5/58 and 4/53, he was all over the Zimbabwe batsmen once again, in the second Test. He was lethal, swinging the ball both ways and inducing mistakes from the batsmen. He took 7/59 in the first innings (which remains his best performance in an innings) to dismiss Zimbabwe for 161 and later returned in the second innings to take another fifer (5/67) as he finished with 12 wickets in the match and 21 wickets in the series.
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