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#4 Ronald Koeman - 46
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Ronald Koeman's record as a penalty taking central defender of Barcelona is flawless.
Quite simply the best goal scoring defender in Liga history, the Dutch maestro was as composed on the ball as he was at making a tackle. He spent 6 seasons in Spain, all with Barcelona, and won the league an impressive 4 times. His return tally of 46 goals from the spot is equally impressive.
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Edited by Amit Mishra
