#3 Joshua Kimmich (Bayern Munich)
If Barcelona have Frenkie De Jong, Bayern Munich have Joshua Kimmich pulling the strings in the middle of the park. The 26-year-old has featured in all games so far under Julian Nagelsmann, providing a calm presence in front of the defensive line.
Goalkeepers and centre-backs aside, Kimmich attempts more long balls than any other outfield Bundesliga player. That also helps him create a plethora of goalscoring chances. After four league games this season, he has averaged 2.5 key passes a game.
Kimmich has three assists to his name this campaign. He could be the midfield general Bayern Munich may need against Barcelona to kick off their Champions League campaign with a win.
#2 Robert Lewandowski (Bayern Munich)
Some things never change. With just four games played in the Bundesliga, Robert Lewandowski is atop the goalscoring charts, scoring six times for Bayern Munich so far.
He was on target in Bayern Munich's 4-1 statement win over RB Leipzig, scoring from the spot. Lewandowski is a goal-scoring threat every time he steps onto the pitch.
The Polish striker also has three assists to his name this campaign. He will look to get on the scoresheet against the Blaugrana, having scored only once in the historic 8-2 drubbing over them last year.
#1 Memphis Depay (Barcelona)
When Barcelona kick off their Champions League campaign on Tuesday, they will be without Lionel Messi, the second-most prolific goalscorer in competition history. But they'll hope that their summer signing, Memphis Depay, steps up against Bayern Munich on Tuesday.
The former Manchester United forward has been in great form in 2021. He is coming off a successful international break with the Netherlands, scoring five goals and picking up an assist.
Barcelona have relied on Depay for goals this season. Depay has scored two of their seven La Liga goals and provided an assist this campaign. He is in great touch, and could be one to watch out for on Tuesday.