Right Winger: Vinicius Junior (Real Madrid)
After struggling for consistency since joining Real Madrid, Vinicius Junior is finally playing to his potential this season. With seven goals and five assists in all competitions so far, the Brazilian is enjoying the finest form of his career.
His finishing skills have been at their deadliest, and the 21-year-old has also linked up with Karim Benzema with devastating effect. Vinicius is finally showing the ability and attitude that earmarked him as a potential star.
Striker: Karim Benzema (Real Madrid)
Much like Vinicius, Karim Benzema has been on fire this season. In fact, he has made the best-ever start to a La Liga campaign by any player, scoring nine times and registering seven assists in eight top-flight games.
With no Lionel Messi or Cristiano Ronaldo this time, the Frenchman has emerged as a favourite for the league's Golden Boot. Having also led Les Blues to Nations League glory recently, he is a contender for the Ballon d'Or award too.
Benzema has scored ten goals in 39 El Clasico games against Barcelona. Considering his blistering current form, he could add to that tally on Sunday.
Left Winger: Memphis Depay (Barcelona)
It's been a promising start to life in Barcelona for Memphis Depay, who arrived from Lyon on a free transfer this summer. He's currently the Blaugrana'd top-scorer in the league, with four strikes to his name.
Even though Barcelona have blown hot and cold this season, the Dutch winger has consistently delivered the goods. He has taken to his new surroundings like a fish to water, taking little time to prove his worth.