4) UFC 206 vs Anthony Pettis

The bout that gave Holloway his first taste of gold in the UFC, the brilliance of his performance against Anthony Pettis cannot be understated. The fight had an odd feel going in as Pettis had missed weight, meaning that only Holloway was eligible to become Interim Featherweight Champion.
However, Holloway didn't allow this to ruin his fight, as he stormed into the cage and took on the former Lightweight champ with great skill. Holloway used his accurate striking and leg kicks to attack and nullify every move thrown at him.
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Finally, in the 3rd round, Holloway changed his status from rising challenger to Champion in the UFC. He used a vital body kick to discombobulate Pettis and pile on a barrage of punches, forcing a stoppage and earning the UFC Interim Featherweight Championship.