#3 Garbine Muguruza
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Garbine Muguruza (ESP) lost to Alison Van Uytvanck (BEL) 7-5, 2-6, 1-6

Going into the match with Garbine Muguruza, Alison Van Uytvanck had won just two of her matches at Wimbledon and had also lost the only meeting between the two. Nobody predicted that the defending champion and the 2015 runner-up would lose the match, but the stats seemed irrelevant.
Muguruza came back from 2-4 down to win the first set, but in the second and the third, it was completely a different story as Alison got into the groove and hit balls exceptionally and took the risks. That also summed up the day as Muguruza did not find her zone.
Edited by Sudeshna Banerjee