#6 Booker T and Goldust

Back in 2002, Booker T and Goldust became yet another of WWE's odd pairings. After being rejected by the nWo, Booker found a companion in Goldust, who joined him to take on the faction. Booker was initially not completely on board with his new ally but eventually warmed up to his oddball ways.
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Joining Goldust marked a face turn from Booker and the duo feuded with the nWo for some time. They then moved on to earn shots at the WWE World Tag Team Championships. After some unsuccessful attempts to become the champs, the pair were victorious at Armadeggon against The Dudley Boyz, Lance Storm & William Regal, and the team of Chris Jericho & Christian.
Goldust and Booker T managed to remain WWE World Tag Team Champions for a few weeks before dropping the titles to Regal and Storm. After they lost the belts, Goldust encouraged his partner to contend for the WWE World Heavyweight Championship and the pair decided to split amicably.