3. Triple H - 168 PPV Matches
Starting the top 3 off is The Game himself, Triple H. The Game made his PPV debut in 1995, defeating Bob Holly at SummerSlam. Triple H was then billed as Hunter Hearst Helmsley and it wouldn't be until 2 years later that he was repackaged as Triple H.
Once he got his momentum and his first main event push, Triple H has rarely been out of the main event. He has been a key element in almost every era since then and is one of the most accomplished superstars in history.
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He has a total of 168 PPV appearances. He is a 14 time World Champion, 5-time Intercontinental Champion, 2-time European Champion, and 3-time Tag Team Champion. He has main evented 7 WrestleManias (16, 18, 20, 21, 22, 25, 32), less than only Hulk Hogan. He won the 2002 and 2016 Royal Rumbles and 1997 King of the Ring tournament.
His last PPV match was at Crown Jewel where he main evented the show in a tag team bout partnering with Shawn Michaels against the Brothers of Destruction. He has main evented a massive 64 events as well.