#2 Batista
Big Dave Batista is now a Hollywood mega-star and retired from pro wrestling after his loss to Triple H at WrestleMania 35. Yet, all through his wrestling career, Batista had some pretty big wins.
While it is true that Batista and Brock Lesnar never faced each other on the WWE main roster, they did square off in WWE's old developmental brand Ohio Valley Wrestling. In the match that took place in September of 2001, Batista pinned Brock with a spear and the two men brawled after the match.
Batista had a rivalry with John Cena in 2010, in a feud between the two men that the company had decided would be top stars in 2005. Dave lost to Cena at WrestleMania 26 but won the WWE Championship a month prior in a strange way.
Vince McMahon announced Cena would defend the title right after being in an Elimination Chamber match. Dave came down to the ring and destroyed Cena before pinning him to become WWE Champion. This was sort of like a Money in the Bank cash-in just without the breifcase.
Batista also had a WrestleMania match against the Undertaker at WrestleMania 23 for the World Heavyweight Championship which he, of course, lost after Taker hit the tombstone piledriver. Dave ended up back with the belt in October of 2007 and faced Taker at Cyber Sunday with a special referee, that man being Stone Cold Steve Austin. Batista pinned Taker after hitting the Batista Bomb and retained the World Heavyweight Championship.