#1 Kane and Lita
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Back in 2004, Matt Hardy got into a feud with Kane, who had set his sights on Lita. Kane fell in love with Lita soon after WrestleMania 20. Lita wasn't interested in him though, which led to Kane kidnapping her. Hardy stepped up to save his girl from Kane. The two fought at Vengeance 2004, with Hardy coming out on top. At SummerSlam 2004, Kane defeated Matt Hardy in a "Till Death Do Us Part" match. Lita was forced to marry Kane as per the stipulation of the match. Kane and Lita got married soon after, on WWE RAW.
As time passed, Lita began getting close to Kane. It all changed in mid-2005, when she turned on The Big Red Machine and revealed her love towards Edge. Kane and Edge began a feud as a result, culminating in a match at Vengeance 2005. Kane defeated Edge at the PPV, and the rivalry came to an end. Edge then began a feud with Matt Hardy, eventually coming out on top this time.