Not real love: Bully Ray and Brooke Hogan
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While many believe Anakin Skywalker and Padme are the worst example of zero on-screen chemistry, we humbly submit the union of Brooke Hogan and Bully Ray for consideration.
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The two seem like total opposites. Brooke was young, from a privileged background, and was a pop starlet in training. Bully Ray was a middle-aged man from the wrong side of the tracks who, while oddly charming, isn't anyone's first choice for a romantic leading man.
The agonizingly bad storyline went on and on, and eventually culminated in a marriage that was nothing but kayfabe. After Bully turned heel Brooke spent several torturous months trying to get a divorce.
Edited by Arvind Sriram