#5 The Big Show
Big Show and Brock Lesnar have faced each other on numerous occasions in the WWE ever since Lesnar made his debut in the promotion back in 2002. But Lesnar's record against The Big Show has been incredibly, losing only once in singles matches.
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The only loss for Lesnar against Show was back in 2002 Survivor Series, which was also the show which hosted the first-ever Elimination Chamber match.
Lesnar, who held the WWE Championship (the Undisputed Championship was renamed as the WWE Championship), after winning it from The Rock earlier that year at SummerSlam, was to defend the title once again at Survivor Series in 2002.
Lesnar had defeated The Undertaker at No Mercy, and bragged about how he could never be defeated, to which Big Show challenged him. The two assaulted each other on SmackDown leading up to their Survivor Series match, and at the show, Big Show defeated Lesnar to win the WWE Championship, as well as inflict Lesnar with his first loss by pinfall.