#1 Mickie James (WWE) and Nick Aldis (National Wrestling Alliance)

Former WWE Women's Champion, Mickie James had got hitched to Nick Aldis in 2015. Aldis used to work for TNA then and he was known as Magnus. However, Nick left the company on June 29, 2015 to try his luck in the indies.
Mickie James, on the other hand, returned to WWE in the year 2016. She had a brief stint in WWE's yellow brand, NXT before she became a member of the main roster. James has not won the women's title after returning but she has been a part of history-making matches like the Women's Royal Rumble Match, the Women's Elimination Chamber Match and she also took part in the first-ever all women's pay-per-view, WWE Evolution.
Did you know a top WWE Superstar just wrestled outside the company? More details HERE
Aldis is currently the NWA World Heavyweight Champion and he is expected to be an important part of NWA in the foreseeable future as well.