#4 Randy Orton (6 appearances, 1 win)
The next three WWE Superstars are tied with six total appearances, so I decided to rank them by number of wins inside the Elimination Chamber. "The Viper" Randy Orton is next on the list having appeared in the second ever Chamber match at SummerSlam in 2003.
Orton was unsuccessful in winning the Chamber match until his last appearance inside the structure in 2014 when he retained the WWE World Heavyweight Championship by defeating Daniel Bryan, John Cena, Cesaro, Christian, and Sheamus.
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With the switch to dual-branded pay per views after WrestleMania this year, you could expect Orton to make his first appearance in five years when the Chamber pay per view comes back around in 2019.