#2 Alexa Bliss and Murphy

Alexa Bliss has made quite the name for herself since being called up to the main roster last summer, quickly capturing the SmackDown Women's Championship at TLC 2016. But prior to that, she had a multi-year stint down in developmental, most of which was spent by the side of Wesley Blake and Buddy Murphy.
The former NXT Tag Team champions were rather bland before being joined by Bliss and together, they made the perfect trio. Part of the reason why they gelled so well might have been because Bliss and Murphy already had chemistry, you know, being in a relationship and all.
Did you know a top WWE Superstar just wrestled outside the company? More details HERE
It was touching when WWE posted footage of Bliss getting drafted to SmackDown Live and her hugging her boyfriend, Murphy. Hopefully, it isn't long before they're reunited on the main roster.