#6 Edge (2009 and 2011)
The Rated-R Superstar Edge won 2 Elimination Chamber matches in his WWE career. His first victory came in 2009 in a match where he was not supposed to compete in the first place. But, he attacked Kofi Kingston before the match to take the superstar's place in the match.
Edge defeated John Cena, Mike Knox, Rey Mysterio, Chris Jericho, and Kane to win the World Heavyweight Championship match inside the Elimination Chamber on the No Way Out pay-per-view of 2009.
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Then in 2011, Edge successfully defended his World Heavyweight Championship against Rey Mysterio, Kane, Drew McIntyre, Big Show, and Wade Barrett to become one of the few superstars to win multiple Elimination Chamber matches in WWE.
Edge has been away from the ring for quite a while now but he makes special appearances on WWE shows along with hosting E & C's Pod of Awesomeness with his friend Christian.