#7 Kane (2010)

After being a staple for WrestleMania for 6 years, Money in the Bank became a staple of its namesake event in 2010, and big surprises emerged from the new pay per view. The biggest of them all was the beginning of the resurgence of 'The Big Red Monster' Kane. Never the top draw in the company despite being a 14-year-old veteran, Kane's surprising victory in the Blue Brand's ladder match brought a new life to his career.
If winning the Briefcase was not enough of a shock for the fans, Kane took it to a whole new level by cashing in on an injured Rey Mysterio less than an hour later, thus winning his first WWE World Title in 12 years. What followed was a 5-month long reign for The Devil's Favourite Demon, which had him feud with the likes of his brother The Undertaker and Edge. His reign also saw the final main event title defence of the World Heavyweight Title.
Did you know a top WWE Superstar just wrestled outside the company? More details HERE
#6 Dean Ambrose (2016)

In 2015 and 2016, there was no wrestler in the whole roster who was more over and popular than Dean Ambrose. Despite being on the losing end of a number of top draw matches against Triple H, Seth Rollins, Roman Reigns and Brock Lesnar, his popularity was soaring day by day. It was really hard for WWE to ignore this, and he was chosen to win the Money in the Bank in 2016, two years after he narrowly lost the prize to Seth Rollins.
Speaking of Rollins, Ambrose got his revenge on The Architect by pinning him on that very night, just minutes after he had regained the title from Roman Reigns. Ambrose held the title for a good 3 months, defending it against both Rollins and Reigns at Battleground, before dropping it to AJ Styles at Backlash. Since then, Ambrose has had a majestic feud with AJ Styles and captured the Intercontinental Title in January 2017. Out because of injury, Ambrose is expected to make his return in August 2018.